A time-dependent anisotropic model for argillaceous rocks. Application to an underground excavation in Callovo-Oxfordian claystone     

《Computers and Geotechnics》2017

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氟化物固体缓冲剂-交流电弧直读发射光谱法测定化探样品中易挥发与难挥发微量元素   总被引：1，自引：1，他引：0  

王鹤龄  李光一  曲少鹏  钱玉平  仇秀梅  董学林 《岩矿测试》2017,36(4):367-373

应用电弧直读发射光谱法测定化探样品,样品无需消解,采用固体进样的方式可以同时测定多个元素。但目前化探分析中常采用的固体缓冲剂(如焦硫酸钾、氟化钠)的电弧温度较低,只能分析银、硼、锡、铅、钼、铜等易挥发元素,而不能分析铬、锰、钛等沸点较高的难挥发性元素。本文通过碱金属控制较低的电弧温度,并利用难挥发元素能在高温条件下与氟离子发生化学反应降低其激发温度,配制了一种以氟化铝、聚三氟氯乙烯等氟化效率较高的化合物为主要成分的固体缓冲剂,通过优化分析线对的选择、曝光时间、电极形状等分析条件,实现了一次制样可同时分析地球化学样品中14种易挥发和难挥发元素。方法检出限为0.016~46.93μg/g,相对标准偏差为4.1%~12.3%,通过国家标准物质验证了准确度,测定值与标准值相符,各项参数都能满足地球化学普查规范要求。本方法分析效率高,在化探分析中具有一定的实用性。  相似文献   

封闭压力酸溶-电感耦合等离子体质谱法同时测定电气石中29种元素   总被引：4，自引：4，他引：0  

成学海  夏传波  郑建业  张文娟  刘晶 《岩矿测试》2017,36(3):231-238

电气石是一种含硼的铝硅酸盐矿物,是重要的非金属矿产资源和成岩成矿作用的灵敏示踪剂,因类质同象置换普遍使其组成成分多变,主量元素为Si、B、Al、Fe和Mg,微量元素有稀土元素、Cu、Pb、Zn、Sn、Ag和Sr等。电气石的化学性质非常稳定,不能被一般的酸或碱完全溶解,本文采用硝酸-氢氟酸封闭压力溶矿,50%王水封闭压力复溶进行样品前处理,建立了电感耦合等离子体质谱法测定电气石中稀有轻金属、重金属、放射性金属、稀土元素等29种元素的分析方法。方法检出限为0.003~0.4μg/g,精密度(RSD,n=12)为0.9%~9.2%;国家标准物质的测定值与标准值基本相符,各元素的加标回收率为95%~105%。本方法解决了电气石样品难分解、复溶时易出现氢氧化铝微细残渣的问题,样品试液中B、Al、Fe等主要共存离子的干扰小,各待测元素测定结果准确、可靠。  相似文献   

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朱程广  郭唐永  邹彤  李世鹏  林强  王雅杰 《大地测量与地球动力学》2013,33(5):150-153

????????????????????????????????????BP???????????????????人???????????????????????????????????BP??????????????????г????????????????????????о??????????BP????????????????????????????????????????????????  相似文献   

IPCC AR4多模式对中国地区未来40 a雪水当量的预估   总被引：3，自引：2，他引：1  

王芝兰  王澄海 《冰川冻土》2012,34(6):1273-1283

通过评估参加CMIP3计划的22 个GCM在20 世纪气候情景(20C3M)下中国地区雪水当量模拟能力的检验, 挑选出模拟能力较好的模式, 通过多模式集合方法, 对SEARS的模拟结果进行集合, 预估未来40 a雪水当量在中国地区的时空变化特征.结果表明: 在A1B情景下和B1情景下, 中国地区未来40 a雪水当量年际变化均呈减少趋势; 在A1B和B1情景下, 青藏高原地区、 华北平原地区、 长江中游地区及东北北部地区的雪水当量均呈减少趋势, 其中在昆仑山西段帕米尔高原地区减少最为显著, 其次为喜马拉雅山区和巴颜喀拉山东段地区.在中国北部的内蒙古高原地区、 云贵高原等部分地区的雪水当量则有所增加.总体上, A1B情景下比B1情景下雪水当量的减少更为明显. 2021-2050年雪水当量在青藏高原减少显著; 对于季节变化来说, 在秋冬季积雪的累积期, 雪水当量可能增加, 尤其在10-12月, 而在积雪消融的春夏季(2-6月)有所减少.  相似文献   

Peak discharge increase in hyperconcentrated floods     

《Advances in water resources》2014

The peak of river floods usually decreases in the downstream direction unless it is compensated by freshwater inflow from tributaries. In the Yellow River (China) the opposite is regularly observed, where the peak discharge of river floods increases in the downstream direction (at a rate far exceeding the contribution from tributaries). This flood peak discharge increase is probably related to rapid morphological changes, to a modified bed friction, or to a combination of both. Yet the relative role of these processes is still poorly understood. This paper aims to analyze the relative contribution of bed erosion and friction change to the peak discharge increase, based on available data and a recently developed numerical model. Using this high-resolution, fully coupled morphodynamic model of non-capacity sediment transport, two hyperconcentrated floods characterized by downstream peak discharge increase are numerically reproduced and analyzed in detail. The results reveal that although erosion effects may contribute to the downstream discharge increase (especially in case of extreme erosion), for most cases the increase must be mainly due to a reduction in bed friction during peak discharge conditions. Additionally, based on the concept of channel storage reduction, the effects of decreasing bed friction and (very strong) bed erosion can be integrated in explaining the peak discharge increase.  相似文献   

流体涡旋中螺旋波不稳定发展的理论研究   总被引：3，自引：0，他引：3       下载免费PDF全文

陶建军  李朝奎 《地球物理学报》2008,51(3):650-656

文章利用柱坐标下的流体涡度方程,通过求初始时刻的解析解,研究了螺旋波的不稳定发展问题.结论是：涡旋中螺旋波动之间可以通过基本流耦合相互作用,出现共振不稳定增长.其增长率大小与初始扰动的波数相关,数值计算结果也表明：波动在发展过程中,螺旋带状结构将越来越明显,螺旋角越来越小.  相似文献   

赣中良山钼矿床流体包裹体特征及其地质意义     

沈滔  陈正乐  潘家永  韩凤彬  伍俊杰  吴玉  王永  周振菊 《现代地质》2016,30(1):17-28

良山钼矿是近年来赣中地区新发现的钼矿,浅部矿体主要赋存于南华系浅变质岩系的构造裂隙中,矿石类型以含辉钼矿石英脉为主。流体包裹体岩相学和显微测温结果表明：含辉钼矿石英脉中的流体包裹体主要呈星散状随机或成群分布,其形态多样,大小集中在2~15 μm,包裹体的类型主要有纯液相包裹体、富气相两相包裹体、富液相两相包裹体和含液体CO₂三相包裹体4类,其中以富液相两相包裹体最为发育;包裹体的均一温度为136~298 ℃,盐度为1.22%~10.11%NaCleqv,密度为0.78~0.99 g/cm3,成矿流体属中-低温、低盐度、较低密度流体;成矿压力估算为13~70 MPa,形成深度为0.5~2.6 km。流体包裹体激光拉曼光谱分析表明：包裹体中气液相成分以H₂O为主,气相中还有少量的CO₂和CO。H、O、S同位素组成显示：成矿流体的δD值介于-61‰~-57.9‰,δ¹⁸OH₂O值介于-3.32‰~-0.52‰,具有岩浆水和大气降水混合的特征;成矿热液中的δ³⁴S值介于-1.8‰~+1.9‰,具有岩浆硫的特征。综合成矿地质特征及相关分析,认为成矿流体可能与燕山期的岩浆活动有关,属于岩浆热液流体,混合作用及钾化作用是促进金属富集沉淀成矿的主要因素,推测矿床属于岩浆热液充填石英脉型钼矿。  相似文献   

Towing dynamics of a liferaft and fast rescue craft in a surface wave     

W. Raman-Nair  J. Power  A. Simoes Re 《Ocean Engineering》2008,35(11-12):1252-1258

The equations of motion for the coupled dynamics of a small liferaft and fast rescue craft in a surface wave are formulated in two dimensions using the methods of Kane and Levinson [1985. Dynamics: Theory and Applications. McGraw-Hill Inc., New York]. It is assumed that the motion normal to the wave surface is small and can be neglected, i.e. the bodies move along the propagating wave profile. The bodies are small so that wave diffraction and reflection are negligible. A Stokes second order wave is used and the wave forces are applied using Morison's equation for a body in accelerated flow. Wind loads are similarly modelled using drag coefficients. The equations are solved numerically using the Runge–Kutta routine “ode45” of MATLAB^®. The numerical model provides guidelines for predicting the tow loads and motions of small craft in severe sea states.  相似文献   

Preindustrial, historical, and fertilization simulations using a global ocean carbon model with new parameterizations of iron limitation, calcification, and N₂ fixation     

Konstantin Zahariev  James R. Christian  Kenneth L. Denman 《Progress in Oceanography》2008,77(1):56-82

The Canadian Model of Ocean Carbon (CMOC) has been developed as part of a global coupled climate carbon model. In a stand-alone integration to preindustrial equilibrium, the model ecosystem and global ocean carbon cycle are in general agreement with estimates based on observations. CMOC reproduces global mean estimates and spatial distributions of various indicators of the strength of the biological pump; the spatial distribution of the air-sea exchange of CO₂ is consistent with present-day estimates. Agreement with the observed distribution of alkalinity is good, consistent with recent estimates of the mean rain ratio that are lower than historic estimates, and with calcification occurring primarily in the lower latitudes. With anthropogenic emissions and climate forcing from a 1850-2000 climate model simulation, anthropogenic CO₂ accumulates at a similar rate and with a similar spatial distribution as estimated from observations. A hypothetical scenario for complete elimination of iron limitation generates maximal rates of uptake of atmospheric CO₂ of less than 1 PgC y⁻¹, or about 11% of 2004 industrial emissions. Even a ‘perfect’ future of sustained fertilization would have a minor impact on atmospheric CO₂ growth. In the long term, the onset of fertilization causes the ocean to take up an additional 77 PgC after several thousand years, compared with about 84 PgC thought to have occurred during the transition into the last glacial maximum due to iron fertilization associated with increased dust deposition.  相似文献